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3676

(a) Write the structural formula of:

(i) 2, 2, 4 - trimethylpentane, (ii) ethylmethanoate, (iii) trans 2, 3 - dimethylbut - 2-ene.

(b) Write the structure of the straight-chain compound that is isomeric with 2,2,4 - trimethylpentane.

(c) Write chemical equations to illustrate the oxidation of: (i) a secondary alkanol (ii) a dihydric alkanol.

(d) When-Crushed cassava was warmed with dilute hydrochloric acid, a sweet-tasting compound, D was obtained. When compcund D was treated with the enzyme, zymase and the mixture distilled a clear and colourleCsliduid, E was obtained. When liquid E was warmed with eth anoic acid i n the presence of a few drops of concentrated tetraoxosulphate (V1) acid, a compound F, with fruity smell was obtained

. (i)To what class of compounds does D belong?

(ii) Name E and F

(iii) Write the fun-ctional group in F

(iv) Write the equation for the reaction between E and ethanoic acid in the presence of concentrated tetraoxosulphate (VI) acid.

(v) Name the type of reaction that takes place between E and ethanoic acid.

(e) Arrange the followingcompounds in their correct order of increasing boiling points: CH\(_3\)CH\(_2\)CH\(_2\)OH, CH\(_3\)CH\(_2\)CH\(_2\)CH\(_2\)CH\(_2\)CH\(_3\) and CH\(_2\)CH\(_2\)CH\(_2\)CH\(_3\); Explain the order.

View Answer & Discuss (2) WAEC 1988
3677

(a) An element X is represented as \(^{40}_{20} X\)

(i) How many electrons and how many neutrons are present in the atom of X?

(ii) Write the electronic configuration of the atom

(b) Chlorine, whose atomic number is 17, reacts with the element X to form a compound.

(i) What type of bond is formed between X and chlorine?

(ii) Explain how the bond between X and chlorine is formed

(iii) Write the formula of the compound formed and statelhree properties of the compound.

(c) Chlorine has two isotopes of mass numbers 35 and 37 respectively. Suggest the possible relative molar masses of a chlorine molecule.

(d) Calculate the mass of one atom of carbon, given that one mole of carbon weighs 12.0g. (L = 6.02 x 10\(^{23}\))

View Answer & Discuss WAEC 1988
3678

A secondary alkanol can be oxidized to give an?

  • A. alkanone
  • B. alkyne
  • C. alkanoic acid
  • D. alkanal
View Answer & Discuss (10) JAMB 2019
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3679

Which of the following will give a precipitate with an aqueous solution of copper (I) chloride?

  • A. But-2-ene
  • B. But-1-ene
  • C. But-2-yne
  • D. But-1-yne
View Answer & Discuss (4) JAMB 2019
3680

The IUPAC name for CH\(_3\)CH\(_2\)COOCH\(_2\)CH\(_3\) is

  • A. methylpropanoate
  • B. ethylethanoate
  • C. ethylpropanoate
  • D. methylethanoate
View Answer & Discuss (6) JAMB 2019
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