(a)(i) Outline a suitable procedure for the preparation of ZnCl\(_2\) crystals stating from zinc granules.
(ii) Write a balanced equation for the reaction in (a)(i).
(b) Considei' the following solutions: Na\(_2\)SO\(_{4(aq)}\), CH3COOK\(_{(aq)}\), Pb(NO\(_3\))\(_{2(aq)}\) and MgCl\(_2\). Which of them has/have a pH
(i) greater than 7;
(ii) equal to 7;
(iii) less than 7?
(c)(i) Determine the oxidation number of Mn in I. MnO\(_2\); II. KMnO\(_4\).
(ii) State one laboratory use of each of the .compounds in (c)(i).
(d) Explain why oxidation and reduction processes are complementary.
(e) Consider the reaction represented by the equation: Fe\(_{(s)}\) + 2Ag\(^+_{(aq)}\) \(\to\) Fe\(^{2+}_{(aq)}\) + 2Ag\(_{(s)}\)
(i) Write a balanced ionic half equations for the reaction.
(ii) Which of the species is I. oxidized; II. reduced?
(iii) State the change in the oxidation number of silver during the reaction.
(ii) Give the mathematical expression of Boyle's law.
(iii) Sketch the graphical representation of Boyle's law.
(b) A given mass of gas occupied 500 cm3 at 30°C and 6.5 x 104 Nm\(^{-2}\). Calculate the volume of the gas at s.t.p. [ Standard pressure = 1.01 x 105 Nm\(^{-2}\)]
(c) Explain why an inflated balloon expands in warm water.
(d)(i) What is meant by the term vapour density? (ii) Determine the vapour density of SO\(_{2}\). [ S = 32, O = 16 ]
(e)(i) Which of the following gases, SO\(_{2}\) and NH\(_{3}\) can be collected by I. upward delivery; II. downward delivery?
(ii) What would be the nature of the solution formed by dissolving each of the following substances in water separately. I. SO\(_{2}\) II. NH\(_{3}\)
(iii) State the property exhibited by SO\(_{2}\) and NH\(_{3}\) in the following equations:
I. 2H\(_{2}\)S\(_{(aq)}\) + SO\(_{2(g)}\) \(\to\) 3S\(_{(s)}\) + 2H\(_{2}\)O\(_{(/)}\)
II. 3CuO\(_{(s)}\) + 2NH\(_{3(g)}\) \(\to\) 3Cu\(_{(s)}\) + 3H\(_{2}\)O\(_{(/)}\) + N\(_{2(s)}\).
(f) State two alloys of tin.
(ii) Give one use of each of the alloys in (f)(i).
