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1995 WAEC Chemistry Theory (a) What is the change in oxidation state of chromium in the reaction represented by...

Chemistry
WAEC 1995

(a) What is the change in oxidation state of chromium in the reaction represented by the following equation?

3SO\(_2\) + Cr\(_2\)O\(^2_{-7}\) + 2H\(^+\)  -> 3SO\(_4^{2-}\) + 2Cr\(^{3+}\) + H\(_2\)O

(b) Use the half equations given below to deduce the equation for the reaction between iron(II) ions and heptaoxodichromate (VI) ions in acidic solution.

Fe\(^{2+}\)  --> Fe\(^{3+}\) + e\(^-\)

Cr\(_2\)O\(^{2-}_7\) + 14H\(^+\) + 6e\(^-\) ----> 2Cr\(^{3+}\) + 7H\(_2\)O.

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Explanation

(a) From +6 to +3

(b) The reaction involves the transfer of 6 electrons from 6Fe  2+ to Cr\(_2\)O\(_7\)

SO, 6Fe\(^{2+}\) \(\rightleftharpoons\) 6Fe\(^{3+}\) + 6e\(^-\)

The addition of the 2 half cell equations gives Cr\(_2\)O\(_7^{2-}\) + 14H\(^+\) — 6Fe\(^{2+}\) \(\to\) 2Cr\(^{3+}\) + 6Fe\(^{3+}\) + 6Fe\(^{3+}\) + 7H\(_2\)O.


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Post-UTME Past Questions - Original materials are available here - Download PDF for your school of choice + 1 year SMS alerts
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Post-UTME Past Questions - Original materials are available here - Download PDF for your school of choice + 1 year SMS alerts
WAEC May/June 2024 - Practice for Objective & Theory - From 1988 till date, download app now - 99995
WAEC Past Questions, Objective & Theory, Study 100% offline, Download app now - 24709
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