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If 30cm\(^3\) of oxygen diffuses through a porous pot in 7 seconds, how long will...

Chemistry
JAMB 1978

If 30cm\(^3\) of oxygen diffuses through a porous pot in 7 seconds, how long will it take 60cm\(^3\) of chlorine to diffuse through the same pot, if the vapour densities of oxygen and chlorine are 16 and 36 respectively?

  • A. 9.3 sec
  • B. 14 sec
  • C. 21 sec
  • D. 28 sec
  • E. 30.3 sec
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Correct Answer: Option C
Explanation

According to Graham's law of diffusion of gases,the rate of diffusion of a gas is proportional to the square root of the density.

From the question, the given parameters are:

Volume of Oxygen, V\(_o\) = 30cm\(^3\), Time of diffusion of Oxygen, t\(_o\) = 7s, Vapour density of Oxygen, d\(_o\) = 16

Volume of Chlorine, V\(_c\) = 60cm\(^3\), Time of diffusion of chlorine, t\(_c\) = ?,  Vapour density of Chlorine, d\(_c\) = 36

\(\frac{t_o}{t_c}\) = \(\sqrt{\frac{d_o}{d_c}}\)

\(\frac{7}{t_c}\) = \(\sqrt{\frac{16}{36}}\)

\(\frac{7}{t_c}\) = \(\frac{4}{6}\)

t\(_c\) = \(\frac{7}{4}\times {6}\)

t\(_c\) = \(\frac{21}{2}\)

Recall that the volume of Chlorine is twice that of Oxygen. Hence, t\(_c\) = 2t\(_o\)

t\(_c = 2\times \frac{21}{2}\) 

t\(_c\) = 21sec - Option C


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