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1996 WAEC Chemistry Practical Credit will be given for strict adherence to instructions, for observations precisely recorded, and for...

Chemistry
WAEC 1996

Credit will be given for strict adherence to instructions, for observations precisely recorded, and for accurate inferences. All tests, observations, and inferences must be clearly entered in your answer book, in ink at the time they are made.

C and D are samples of two simple salts. Carry out the following exercises on them. Record your observations and identify any gases evolved. State the conclusion you draw from the result of each test.

(a) Put all of C in a test tube and heat strongly for about 3 to 5 minutes. Allow the residue to cool.

(b) Add about 5cm\(^3\) of distilled water to the residue from (a) above. Shake and test with litmus paper. 

 

 

 

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Explanation
Test Observation Inference
(a) C + heat 

Colourless, odourless gas turned lime water milky/turbid vapour condenses at the neck of the test tube.

White residue is left 

Gas in CO\(_2\) from CO\(_2^{2-}\) or HCO\(_{3-}\) 
(b) Residue from a + water + litmus  Dissolved to form a colourless solution turned red litmus to blue 

Alkaline solution 

 

(c) D + water  Dissolved to form colourless solution  Pb\(^{2-}\) or Al\(^{3+}\) or Zn\(^{2+}\) or Ca\(^{2+}\) present 
(i) Soln. of D + NaOH\(_{(aq)}\) White ppt.; ppt. soluble pb\(^{2+}\) or Al\(^{3+}\) or Zn\(^{2+}\) 
(ii) Soln.of D +  NH\(_{3(aq)}\) in drops then in excess 

White ppt. 

ppt. soluble 

pb\(^{2+}\) or Al\(^{3+}\)

(iii) Soln of D + HCl 

ppt. heated, on cooling 

White ppt. 

ppt. dissolves/disappears

ppt. reappears

ppt. is PbCl\(_2\)

pb\(^{2+}\) present 

 


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