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2016 WAEC Chemistry Practical All your burette readings (initials and final) as well as the size of your pipette must be...

Chemistry
WAEC 2016

All your burette readings (initials and final) as well as the size of your pipette must be recorded but no account of experimental procedure is required. All calculations must be done in your answer booklet 

C is a mıxture of two salts, containing one cation and two anions. Carry out the following exercises on C. Record your observations and identify any gas(es) evolved. State the conclusion you draw from the result of each test.

(a) Put all of C in a beaker and add about 10 cm\(^3\) of distilled water. Stir well and filter. Keep the filtrate and the residue.

(b) To about 2 cm\(^3\) of the filtrate, add few drops of AgNO\(_{(aq)}\), followed by HNO\(_{3(g)}\). Add excess NH\(_{3(aq)}\) to the resulting mixture.

(c)(i) Put all of the residue into a clean test tube and add about 5 cm of HNO\(_{3(aq)}\)

(ii) To about 2 cm\(^3\) of the solution from 2(c)(i), add NaOH\(_{(aq)}\) in drops and then in excess

(iii) To another 2 cm\(^3\) of the solution from 2(c)(i), add NH\(_{3(aq)}\) in drops and then in excess.

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Explanation
  Test Observation Inference
(a) C\(_{(s)}\) + distilled water + filter  Party dissolved/soluble colourless filtrate obtained, water residue  C contains soluble and insoluble salts
(b)

Filtrate C + AgNO\(_{3(aq)}\)

+ HNO\(_{3(aq)}\)

+ NH\(_{3(aq)}\)

White precipitate 

Precipitate insoluble 

Precipitate soluble/dissolved

Cl\(^{-}\) or CO\(_3^{2-}\) or SO\(_3^{2-}\)

Cl\(^-\) 

Cl\(^-\) present

(c)(i) Residue + HNO\(_{3(aq)}\)

Effervescence, colourless,

Odourless gas evolved 

Gas turned lime water milky 

 

 

CO\(_2\) gas from CO\(_3^{2-}\) evolved

(ii)

Solution from C(i) + 

NaOH\(_{3(aq)}\) drops

Then in excess

White gelatinous precipitate 

Precipitate dissolved/soluble

Zn\(^{2+}\) or Al\(^{3+}\) present
(iii)

Solution from C(i) + NH\(_{3(aq)}\) drops 

Then in excess

White gelatinous precipitate 

Precipitate dissolved/soluble

Zn\(^{2+}\) or Al\(^{3+}\) present 

Zn\(^{2+}\) present 

 


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Post-UTME Past Questions - Original materials are available here - Download PDF for your school of choice + 1 year SMS alerts
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