Which of the following reagents could be used to distinguish between propan-1-ol and propan-2-ol ?
The reagent I\(_2\) / OH\(^-\) (iodine in alkaline solution) is used for the iodoform test, which identifies compounds containing a methyl ketone group or a methyl hydroxy group (specifically a secondary alcohol with the structure CH\(_3\)CH(OH)R).
Propan-2-ol is a secondary alcohol (CH\(_3\)CH(OH)CH\(_3\)) that possesses the required methyl group adjacent to the hydroxyl-bearing carbon. It reacts with I\(_2\) / OH\(^-\) to produce a characteristic yellow precipitate of iodoform (
CHI\(_3\).
Propan-1-ol is a primary alcohol (CH\(_3\)CH\(_2\)CH\(_2\)OH) and does not have this specific structure. Consequently, it gives a negative result (no yellow precipitate)
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