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2002 WAEC Chemistry Theory (a) What is the shape of (i) p - orbital; (ii) a molecule of methane;...

Chemistry
WAEC 2002

(a) What is the shape of (i) p - orbital; (ii) a molecule of methane; (iii) a molecule of carbon (IV) oxide?

 

(b) Consider the following elements: Ne, S, CI, 0, Fe, Mg. State which of them

(i) exhibit(s) allotropy;

(ii) form(s) coloured ions;

(iii) is/are malleable;

(iv) consist(s) of molecules that are far apart at room temperature;

(v) form(s) hydrides by sharing electrons with hydrogen;

(vi) has/have complete outermost shell.

 

(c)(i) List three applications of radioactivity in different fields.

(ii) Explain clearly the difference between the following reactions involving electron loss from lead.

\(^{211} pb\) \(\to\) \(^{ 211}Bi\) + \(^0_{-1}\); Pb \(\to\)  pb\(^{3+}\) _ 2e\(^-\)

(iii) Give one advantage and one disadvantage of nuclear power generation over the use of fossil fuels.

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Explanation

(a)(i) P=orbital are mutually perpendicular dumb-bell shaped lobes.

(ii) Methane is tetrahedral

(iii) Carbon (IV) oxide is linear.

 

(b)(i) Sulphur exhibits allotropy

(ii) Fe

(iii) Fe and Mg

(iv) Ne, CI, O

(v) Mg

(vi)Ne.

 

(c)(i) —Medical uses

— Sterilization

— Industrial uses

—Agricultural purposes

— Radioactive tracers

— Dating techniques

(ii) \(^{211} pb\) \(\to\) \(^{ 211}Bi\) + e is a radioactive reaction. It involves the production of beta particles and transmutation of Pb to Bi.

Pb --> Pb\(^{2+}\) + 2e\(^-\) is an ionisation reaction where Pb lost two electrons (oxidation) to become Pb\(^{2+}\).

(iii) Advantage: Nuclear power generation can work day and night for a few years with the same uranium fuel. Disadvantage: It is too expensive to install when compared with fossil fuels.


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WAEC Past Questions, Objective & Theory, Study 100% offline, Download app now - 24709
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WAEC offline past questions - with all answers and explanations in one app - Download for free
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WAEC May/June 2024 - Practice for Objective & Theory - From 1988 till date, download app now - 99995