Consider the reaction represented by the equation: 2SO\(_{2(g)}\) + O\(_{2(g)}\) ⇌ 2SO\(_{3(g)}\); ∆H = -...

WAEC 2006

Consider the reaction represented by the equation: 2SO\(_{2(g)}\) + O\(_{2(g)}\) ⇌ 2SO\(_{3(g)}\); ∆H = - 197 kJmol\(^{-1}\). Which of the following conditions will not increase the yield of sulphur (VI) oxide?

A. Increase in temperature
B. Decrease in temperature
C. Increase in pressure
D. Addition of O₂ into the mixture

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Correct Answer: Option A

Explanation

The reaction is an exothermic reaction (∆H=-197kjmol).
For continual yield of sulphur(IV)oxide, heat must be liberated.
So,increasing the temperature of the reaction will lead to reduction in yield of \(SO_3\) since it favours backward reaction which is endothermic.

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