Which of the following can be added to dissolve the precipitate formed in the reaction represented by the following equation? CaCl2(aq) + H2C2O 4(s) ⇌ CaC 2O2
Calcium chloride solution
Concentrated hydrochloric acid
Ethanol
Ethanedioc acid
Aqueous ammonia
Explanation
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The correct answer is:
D. Ethanedioic acid
Explanation:
The reaction in the question forms calcium oxalate, which is a slightly soluble salt. To dissolve the precipitate, you need to shift the equilibrium to the right. Adding ethanedioic acid increases the concentration of oxalate ions( C2O4-), which promotes the dissolution of the precipitate through a common ion effect.
Why not the other options?
A. Calcium chloride solution: Adding more calcium ions would shift the equilibrium toward more precipitate formation.
B. Concentrated hydrochloric acid: HCl may not directly dissolve the precipitate, and it could disrupt the equilibrium in an unpredictable way.
C. Ethanol: Ethanol is nonpolar and does not affect the equilibrium of a salt in aqueous solution.
E. Aqueous ammonia: Ammonia does not react with calcium oxalate or shift this equilibrium effectively.

The answer is really B. Calcuim oxolate, the precipitate formed dissolves in ammonia buh not in any of the other options mentioned



