Post UTME Past Questions Agent
WAEC and NECO CBT App for Mobile Devices - Candidates, Schools, Centres, Resellers - 100% Offline -Download Now

The salt that will form a precipitate soluble in excess ammonia solution is

Chemistry
JAMB 2003

The salt that will form a precipitate soluble in excess ammonia solution is

  • A. Ca(NO3)2
  • B. Cu(NO3)2
  • C. Mg(NO3)2
  • D. Al(NO3)3
Your School's Whatsapp Group - Join Us now
Post UTME Past Questions Agent
WAEC and NECO CBT App for Mobile Devices - Candidates, Schools, Centres, Resellers - 100% Offline -Download Now
Correct Answer: Option B
Explanation

When ammonia is added to a copper(II) nitrate solution, a pale blue precipitate of copper(II) hydroxide (Cu(OH)2) forms. The balanced equation for this reaction is

      Cu(NO\(_3\))\(_2\)  +  2NH\(_4\)OH→Cu(OH)2↓ +  2NH\(_4\)NO\(_3\)

Excess ammonia: When more ammonia is added, the precipitate dissolves and forms a deep blue solution of tetraammine copper(II) nitrate. The balanced equation for this reaction is   Cu(OH)2(s)+4NH3(aq)−⇀↽−[Cu(NH3)4]+2(aq)+2OH−(aq)

This happens because the addition of more ammonia causes the formation of a coordination complex cation of copper(II) bonded to four ammonia molecules. This shifts the solubility equilibrium of copper(II) hydroxide to the right, causing the precipitate to dissolve.

There is an explanation video available below.


Report an Error Ask A Question Download App
WAEC and NECO CBT Software for Computers and Laptops - Candidates, Schools, Centres, Resellers - 100% Offline -Download Now
WAEC and NECO CBT App for Mobile Devices - Candidates, Schools, Centres, Resellers - 100% Offline -Download Now
Your School's Whatsapp Group - Join Us now

Explanation Video

Your School's Whatsapp Group - Join Us now
Post UTME Past Questions Agent
Post-UTME Past Questions - Original materials are available here - Download PDF for your school of choice + 1 year SMS alerts

Contributions ({{ comment_count }})

Please wait...

{{ settings.no_comment_msg ? settings.no_comment_msg : 'There are no comments' }}

Quick Questions

Post your Contribution

Please don't post or ask to join a "Group" or "Whatsapp Group" as a comment. It will be deleted. To join or start a group, please click here

{{ quote.posted_by.display_name }}
{{ settings.form_textarea_description }}
 
WAEC and NECO CBT App for Mobile Devices - Candidates, Schools, Centres, Resellers - 100% Offline -Download Now
Your School's Whatsapp Group - Join Us now
WAEC and NECO CBT Software for Computers and Laptops - Candidates, Schools, Centres, Resellers - 100% Offline -Download Now
Post UTME Past Questions Agent
Post-UTME Past Questions - Original materials are available here - Download PDF for your school of choice + 1 year SMS alerts
Post-UTME Past Questions - Original materials are available here - Download PDF for your school of choice + 1 year SMS alerts
WAEC and NECO CBT Software for Computers and Laptops - Candidates, Schools, Centres, Resellers - 100% Offline -Download Now
WAEC and NECO CBT App for Mobile Devices - Candidates, Schools, Centres, Resellers - 100% Offline -Download Now
Post UTME Past Questions Agent