If 30cm\(^3\) of oxygen diffuses through porous plug in 7s, how long will it take 60 cm\(^3\) of chlorine to diffuse through the same plug?
12s
14s
21s
30s
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According to Graham's Law of Diffusion:
Rate of diffusion β 1/βMolecular weight
Since Oxygen (O2) has a molecular weight of 32 and Chlorine (Cl2) has a molecular weight of 70.9:
Rate of diffusion of O2 / Rate of diffusion of Cl2 = β(70.9/32) = β2.215 β 1.487
Now, let's use the given data:
Time taken for 30 cmΒ³ of O2 to diffuse = 7 secs
We need to find the time taken for 60 cmΒ³ of Cl2 to diffuse:
Since the volume of Cl2 is twice that of O2, and the rate of diffusion is 1.487 times slower:
Time taken for 60 cmΒ³ of Cl2 to diffuse β 7 secs Γ 2 Γ 1.487 β 20.8 secs = 21 secs
So, it will take 21 secs for 60cm3 of Chlorine to diffuse through the same plug.

Let Rcl be the rate of difussion of Chlorine and Ro be the rate of diffusion of oxygen
and recall that Graham's law states that: the rate of diffusion is inversely proportional to the square root of it's molar mass
so we have
Ro/Rcl=(βMcl)/(βMo)
Ro=30/7,Rcl=60/x,Mcl= 71,Mo= 32
Therefore substituting we have;
(30/7)/(60/x)=(β71)/(β32)
30/7 Γ X/60 = 1.5
X/14 =1.5
X = 14Γ1.5
X=21secs
Therefore it will take 21seconds for 60cm3 of Chlorine to diffuse through the porous plug.

30 of oxygen = 7sec
60 of chlorine = x
T1 = 14
molecular mass of chlorine = 35.5 * 2
molecular mass of oxygen = 16 *2
T2 = T1 square root M2 over M1
then solve





