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Aromatic and aliphatic hydrocarbons can be distinguished from each other by the?

Chemistry
JAMB 1995

Aromatic and aliphatic hydrocarbons can be distinguished from each other by the?

  • A. action of bromine
  • B. use of polymerization reaction
  • C. action of heat
  • D. use of oxidation reaction
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Correct Answer: Option C
Explanation

Aromatic and aliphatic hydrocarbons are most distinctively distinguished by their behavior when heated or burned. 

Aromatic hydrocarbons (like benzene) have a high carbon-to-hydrogen ratio. When heated to ignition, they burn with a smoky, sooty yellow flame due to incomplete combustion of the high carbon content. Aliphatic hydrocarbons (like alkanes) generally burn with a cleaner, non-sooty flame because they have a higher proportion of hydrogen. 

A. action of bromine: While bromine can distinguish between saturated (alkanes) and unsaturated (alkenes/alkynes) hydrocarbons, it is not the primary way to distinguish aromatic from aliphatic compounds generally. For example, both benzene (aromatic) and many alkanes (aliphatic) are relatively unreactive with bromine under standard conditions, while alkenes (aliphatic) react quickly.

B. use of polymerization reaction: Both aromatic (e.g., styrene) and aliphatic (e.g., ethylene) monomers can undergo polymerization. Therefore, this reaction is not a specific diagnostic test to tell them apart.

D. use of oxidation reaction: Both types of hydrocarbons can be oxidized under various conditions. While the specific products vary, oxidation is not used as a standard, simple laboratory test to distinguish the two classes.


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