Which of these has the most complex level of organization?

The levels of organization in the human body, from basic to complex are: Cell, Tissue, Organ, System, Organism.

Cells

The most basic unit of life and the smallest unit that can reproduce.
Tissues

A group of similar cells that work together to perform a specific function. The heart's cardiac muscle is a tissue.
Organs

A structure made up of different tissues that perform specific bodily functions. The heart is an organ.
Organ systems

A higher level of organization that consists of functionally related organs. The heart is part of the circulatory system, which also includes blood vessels.As a result, the heart is part of a complex system of organization in the body.